Publications

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Intergranular cracking as a major cause of long-term capacity fading of layered cathodes. H. Liu, M. Wolf, K. Karki, Y.-S. Yu, E. A. Stach, J. Cabana, K. W. Chapman and P. J. Chupas. Nano Lett. 2017, 17, 3452–3457.

Mechanism of Zn insertion into nanostructured δ-MnO2: A nonaqueous rechargeable Zn metal battery. S.-D. Han, S. Kim, D. Li, V. Petkov, H. D. Yoo, P. J. Phillips, H. Wang, J. J. Kim, K. L. More, B. Key, R. F. Klie, J. Cabana, V. R. Stamenkovic, T. T. Fister, N. M. Markovic, A. K. Burrell, S. Tepavcevic and J. T. Vaughey. Chem. Mater. 2017, 29, 4874–4884.

Direct characterization of the Li intercalation mechanism into a-V2O5 nanowires using in-situ transmission electron microscopy. A. Mukherjee, H. A. Ardakani, T. Yi, J. Cabana, R. Shahbazian-Yassar and R. F. Klie. Appl. Phys. Lett. 2017, 110, 213903

Visualization of electrochemical reactions in battery materials with X-ray microscopy and mapping. M. Wolf, B. M. May, J. Cabana. Chem. Mater. 2017, 29, 3347–3362.

Investigating the intercalation chemistry of alkali ions in fluoride perovskites. T. Yi, W. Chen, L. Cheng, R. D. Bayliss, F. Lin, M. R. Plews, D. Nordlund, M. M. Doeff, K. A. Persson and J. Cabana. Chem. Mater. 2017, 29, 1561–1568.

Near-edge X-ray refraction fine structure microscopy. M. Farmand, R. Celestre, P. Denes, A. L. D. Kilcoyne, S. Marchesini, H. Padmore, T. Tyliszczak, T. Warwick, X. Shi, J. Lee, Y.-S. Yu, J. Cabana, J. Joseph, H. Krishnan, T. Perciano, F. R. N. C. Maia and D. Shapiro. Appl. Phys. Lett. 2017, 110, 063101.

Visualization of the phase propagation within carbon-free Li4Ti5O12 battery electrodes. C. Kim, Y.-S. Yu, B. Moyon, C. Sirisopanaporn, T. J. Richardson and J. Cabana. J. Phys. Chem. C 2016, 120, 29030–29038.

“Rocking-Chair”-type metal hybrid supercapacitors. H. D. Yoo, S.-D. Han, R. D. Bayliss, A. A. Gewirth, B. Genorio, N. N. Rajput, K. A. Persson, A. K. Burrell and J. Cabana. ACS Appl. Mater. Interfaces 2016, 8, 30853–30862. 

Lithium metal-copper vanadium oxide battery with a block copolymer electrolyte. D. Devaux, X. Wang, J. L. Thelen, D. Y. Parkinson, J. Cabana, F. Wang and N. P. Balsara. J. Electrochem. Soc. 2016, 163, A2447–A2455.

Atomic defects during ordering transitions in LiNi0.5Mn1.5O4 and their relationship with electrochemical properties. M. Casas-Cabanas, C. Kim, J. Rodriguez-Carvajal and J. Cabana. J. Mater. Chem. A 2016, 4, 8255–8262.

Structure and sodium ion dynamics in sodium strontium silicate investigated by multinuclear solid-state NMR. K. Inglis, J. P. Corley, P. Florian, J. Cabana, R. D. Bayliss and F. Blanc. Chem. Mater. 2016, 28, 3850−3861.

Graphene quantum dots: structural integrity and oxygen functional groups for high sulphur/sulphide utilization in lithium sulphur batteries. J. Park, J. Moon, C. Kim, J. H. Kang, E. Lim, J. Park, K. J. Lee, S.-H. Yu, J.-H. Seo, J. Lee, J. Heo, T. Nobuo, S.-P. Cho, J. Pyun, J. Cabana, B. H. Hong and Y.-E. Sung. NPG Asia Mater. 2016, 8, e272.

Phase-controlled electrochemical activity of epitaxial Mg-spinel thin films. X. Feng, X. Chen, L. Qiao, A. L Lipson, T. T Fister, L. Zeng, C. Kim, T. Yi, N. Sa, D. Proffit, A. K Burrell, J. Cabana, B. J. Ingram, M. D. Biegalski, M. Bedzyk, P. Fenter. ACS Appl. Mater. Interfaces 2015, 7, 28438–28443.

Dependence on crystal Size of the nanoscale chemical phase distribution and fracture in LixFePO4. Y.-S. Yu, C. Kim, D. A. Shapiro, M. Farmand, D. Qian, T. Tyliszczak, A. L. D. Kilcoyne, R. Celestre, S. Marchesini, J. Joseph, P. Denes, T. Warwick, F. C. Strobridge, C. P. Grey, H. Padmore, Y. S. Meng, R. Kostecki and J. Cabana. Nano Lett. 2015, 15, 4282–4288.

Direct observation of reversible magnesium ion intercalation into a spinel oxide host. C. Kim, P. J. Phillips, B. Key, T. Yi, D. Nordlund, Y.-S. Yu, R. D. Bayliss, S.-D. Han, M. He, Z. Zhang, A. K. Burrell, R. F. Klie and J. Cabana. Adv. Mater. 2015, 27, 3377–3384.

Visualization of electrochemically driven solid-state phase transformations using operando hard X-ray spectro-imaging. L. Li, Y.-C. K. Chen-Wiegart, J. Wang, P. Gao, Q. Ding, Y.-S. Yu, F. Wang, J. Cabana, J. Wang and S. Jin. Nat. Commun. 2015, 6, 6883.

Nonequilibrium pathways during electrochemical phase transformations in single crystals revealed by dynamic chemical imaging at nanoscale resolution. Y.-S. Yu, C. Kim, Y. Liu, A. van der Ven, Y. S. Meng, R. Kostecki and J. Cabana. Adv. Energy Mater. 2015, 5, 1402040.

The formation mechanism of fluorescent metal complexes at the LixNi0.5Mn1.5O4−δ/carbonate ester electrolyte interface. A. Jarry, S. Gottis, Y.-S. Yu, J. Roque-Rosell, C. Kim, J. Cabana, J. Kerr and R. Kostecki. J. Am. Chem. Soc. 2015, 137, 3533-3539.

High-voltage cathode materials for lithium-ion batteries: freeze-dried LiMn0.8Fe0.1M0.1PO4/C (M = Fe, Co, Ni, Cu) nanocomposites. A. Iturrondobeitia, A. Goñi, I. Gil de Muro, L. Lezama, C. Kim, M. M. Doeff, J. Cabana and T. Rojo. Inorg. Chem. 2015, 54, 2671-2678.

Effects of crystallinity and impurities on the electrical conductivity of Li–La–Zr–O thin films. J. S. Park, L. Cheng, V. Zorba, A. Mehta, J. Cabana, G. Chen, M. M. Doeff, T. J. Richardson, J. H. Park, J.-W. Song and W.-S. Hong. Thin Solid Films 2015, 576, 55–60.

Stabilization of battery electrode/electrolyte interfaces employing nanocrystals with passivating epitaxial shells. C. Kim, P. J. Phillips, L. Xu, A. Dong, R. Buonsanti, R. F. Klie and J. Cabana. Chem. Mater. 2015, 27, 394–399.

Asymmetric pathways in the electrochemical conversion reaction of NiO as battery electrode with high storage capacity. U. Boesenberg, M. A. Marcus, A. K. Shukla, T. Yi, E. McDermott, P. F. Teh, M. Srinivasan, A. Moewes and J. Cabana. Sci. Rep. 2014, 7133.

Understanding the defect chemistry of alkali metal strontium silicate solid solutions: insight from experiment and theory. R. D. Bayliss, S. N. Cook, D. O. Scanlon, S. Fearn, J. Cabana, C. Greaves, J. A. Kilner and S. J. Skinner. J. Mater. Chem. A 2014, 2, 17919-17924.

Chemical composition mapping with nanometer resolution by soft X-ray microscopy. D. A. Shapiro, Y.-S. Yu, T. Tyliszczak, J. Cabana, R. Celestre, W. Chao, K. Kaznatcheev, A. L. D. Kilcoyne, F. Maia, S. Marchesini, Y. S. Meng, T. Warwick, L. Yang and H. Padmore. Nat. Photon. 2014, 8, 765–769.

Electroanalytical study of the viability of conversion reactions as energy storage mechanisms. A. Ponrouch, J. Cabana, R. Dugas, J. L. Slack and M. R. Palacín. RSC Adv. 2014, 4, 35988-35996.

The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes. L. Cheng, E. J. Crumlin, W. Chen, R. Qiao, H. Hou, S. F. Lux, V. Zorba, R. Russo, R. Kostecki, Z. Liu, K. Persson, W. Yang, J. Cabana, T. J. Richardson, G. Chen and M. M. Doeff, Phys. Chem. Chem. Phys. 2014, 16, 18294-18300.

Fingerprinting lithium-sulfur battery reaction products by X-ray absorption spectroscopy. K. H. Wujcik, J. J. Velasco-Velez, C. H. Wu, T. A. Pascal, A. A Teran, M. A Marcus, J. Cabana, J. Guo, D. Prendergast, M. Salmeron and N. P. Balsara. J. Electrochem. Soc. 2014, 161, A1100-A1106.

Surface chemistry consequences of Mg-based coatings on LiNi0.5Mn1.5O4 electrode materials upon operation at high voltage. G. Alva , C. Kim , T. Yi , J. Cook , L. Xu, G. Nolis and J. Cabana. J. Phys. Chem. C 2014, 118, 10596–10605.

Ultrathin lithium ion conducting coatings for increased interfacial stability in high voltage Li-ion batteries. J. S. Park, X. Meng, J. W. Elam, S. Hao, C. Wolverton, C. Kim and J. Cabana. Chem. Mater. 2014, 26, 3128–3134.

Electron tomography analysis of reaction path during formation of nanoporous NiO by solid state decomposition. A. Shukla, P. Ercius, A. Gautam, J. Cabana, and U. Dahmen. Cryst. Growth Des. 2014, 14, 2453–2459.

X-ray absorption spectra of dissolved polysulfides in lithium–sulfur batteries from first principles. T. A. Pascal, K. H. Wujcik, J. J. Velasco-Velez, C.-H. Wu, A. A. Teran, M. Kapilashrami, J. Cabana, J. Guo, M. Salmeron, N. P. Balsara and D. G. Prendergast. J. Phys. Chem. Lett. 2014, 5, 1547–1551.

Lepidocrocite-type layered titanate structures: new lithium and sodium ion intercalation anode materials. M. Shirpour, J. Cabana and M. M. Doeff. Chem. Mater. 2014, 26, 2502–2512.

Toward general rules for the design of battery electrodes based on titanium oxides and free of conductive additives. C. T. Alexander, C. Kim, R. Yaylian and J. Cabana. Energy Technol. 2014, 2, 383–390.

Modification of the electrochemical activity of LiMn1.95Si0.05O4 spinel via addition of phases with different physico-chemical properties. A. Iturrondobeitia, A. Goñi, L. Lezama, C. Kim, M. M. Doeff, J. Cabana and T. Rojo. J. Mater. Chem. A 2014, 2, 3216-3222.

Titanate anodes for sodium ion batteries. M. M. Doeff, J. Cabana and M. Shirpour. J. Inorg. Organomet. Polym. 2014, 24, 5-14.

Effective wrapping of graphene on individual Li4Ti5O12 grains for high-rate Li-ion batteries. Y. Oh, S. Nam, S. Wi, J. Kang, T. Hwang, S. Lee, H. H. Park, J. Cabana, C. Kim and B. Park. J. Mater. Chem. A 2014, 2, 2023-2027.

Finite temperature effects on the X-ray absorption spectra of lithium compounds: first-principles interpretation of X-ray Raman measurements.T. A. Pascal, U. Boesenberg, R. Kostecki, T. J. Richardson, T.-C. Weng, D. Sokaras, D. Nordlund, E. McDermott, A. Moewes, J. Cabana and D. Prendergast. J. Chem. Phys. 2014, 140, 034107.

Effect of microstructure and surface impurity segregation on the electrical and electrochemical properties of dense Al-substituted Li7La3Zr2O12.L. Cheng, J. S. Park, H. Hou, V. Zorba, G. Chen, T. J. Richardson, J. Cabana, R. Russo and M. M. Doeff. J. Mater. Chem. A 2014, 2, 172-181.

Electrochemical reactivity with lithium of spinel-type ZnFe2-yCryO4 (0≤y≤2). P. F. Teh, S. S. Pramana, C. Kim, C.-M. Chen, C. H. Chuang, Y. Sharma, J. Cabana and M. Srinivasan. J. Phys. Chem. C 2013, 117, 24213–24223.

Carbon-free TiO2 battery electrodes enabled by morphological control at the nanoscale. C. Kim, R. Buonsanti, R. Yaylian, D. J. Milliron and J. Cabana. Adv. Energy Mater. 2013, 3, 1286–1291.

Effect of Si(IV) substitution on electrochemical, magnetic and spectroscopic performance of nanosized LiMn2-xSixO4. A. Iturrondobeitia, A. Goñi, L. Lezama, C. Kim, M. M. Doeff, J. Cabana and T. Rojo. J. Mater. Chem. A 2013, 1, 10857-10862.

Study of the transition metal ordering in layered NaxNix/2Mn1-x/2O2 (2/3 ≤ x  1) and consequences of Na/Li exchange. J. Cabana, N. A. Chernova, J. Xiao, M. Roppolo, K. A. Aldi, M. S. Whittingham and C. P. Grey. Inorg. Chem. 2013, 52, 8540-8550.

Nanocomposites of titanium dioxide and polystyrene-poly(ethylene oxide) block copolymer as solid-state electrolytes for lithium metal batteries. I. Gurevitch, R. Buonsanti, A. A. Teran, B. Gludovatz, R. O. Ritchie, J. Cabana and N. P. Balsara. J. Electrochem. Soc. 2013, 160, A1611-A1617.

New materials based on a layered sodium titanate for dual electrochemical Na and Li intercalation systems. M. Shirpour, J. Cabana and M. M. Doeff. Energy Environ. Sci. 2013, 6, 2538-2547.

Mesoscale phase distribution in single particles of LiFePO4 following lithium deintercalation. U. Boesenberg, F. Meirer, Y. Liu, A. K. Shukla, R. Dell’Anna, T. Tyliszczak, G. Chen, J. C. Andrews, T. J. Richardson, R. Kostecki and J. Cabana. Chem. Mater. 2013, 25, 1664–1672.

Monodisperse Sn nanocrystals as a platform for the study of mechanical damage during electrochemical reactions with Li. L. Xu, C. Kim, A. K. Shukla, A. Dong, T. M. Mattox, D. J. Milliron and J. Cabana. Nano Lett. 2013, 13, 1800–1805.

Mechanism of phase propagation during lithiation in carbon-free Li4Ti5O12 battery electrodes. C. Kim, N. S. Norberg, C. T. Alexander, R. Kostecki and J. Cabana. Adv. Funct. Mater. 2013, 23, 1214-1222.

The effect of Al substitution on the chemical and electrochemical phase stability of orthorhombic LiMnO2. J. B. Cook, C. Kim, L. Xu and J. Cabana. J. Electrochem. Soc. 2013, 160, A46-A52.

Effect of lithium borate addition on the physical and electrochemical properties of the lithium ion conductor Li3.4Si0.4P0.6O4. L. Zhang, L. Cheng, J. Cabana, G. Chen, M. M. Doeff, and T. J. Richardson. Solid State Ionics 2013, 231, 109–115.

Structural underpinnings of the enhanced cycling stability upon Al-substitution in LiNi0.45Mn0.45Co0.1-yAlyO2 positive electrode materials for Li-ion batteries. T. E. Conry, A. Mehta, J. Cabana and M. M. Doeff. Chem. Mater. 2012, 24, 3307–3317.

Composition-structure relationships in the Li-ion battery electrode material LiNi0.5Mn1.5O4. J. Cabana, M. Casas-Cabanas, F. Omenya, N. A. Chernova, D. Zeng, M. S. Whittingham and C. P. Grey. Chem. Mater. 2012, 24, 2952-2964.

XAFS Investigations of LiNi0.45Mn0.45Co0.1-yAlyO2 positive electrode materials. T. E. Conry, A. Mehta, J. Cabana and M. M. Doeff. J. Electrochem. Soc. 2012, 159, A1562-A1571.

Electronic structure study of ordering and interfacial interaction in graphene/Cu composites. L. Zhang, E. Pollak, W.-C. Wang, P. Jiang, P.-A. Glans, Y. Zhang, J. Cabana, R. Kostecki, C. Chang, M. Salmeron, J. Zhu and J. Guo. Carbon 2012, 50, 5316–5322.

Investigation of cation ordering in triclinic sodium birnessite via 23Na MAS NMR spectroscopy. K. A. Aldi, J. Cabana, P. J. Sideris, J. Kim and C. P. Grey. Amer. Miner. 2012, 97, 883-889.

Crystal structure, physical properties and electrochemistry of copper substituted LiFePO4 single crystals. S. Upreti, N. A. Chernova, J. Xiao, J. K. Miller, O. V. Yakubovich, J. Cabana, C. P. Grey, V. L. Chevrier, G. Ceder, J. L. Musfeldt and M. S. Whittingham. Chem. Mater. 2012, 24, 166-173.

Effect of ball-milling and lithium insertion on the lithium mobility and structure of Li3Fe2(PO4)3. J. Cabana, J. Shirakawa, M. Nakayama, M. Wakihara and C. P. Grey. J. Mater. Chem. 2011, 21, 10012-10020.

Three-dimensional imaging of chemical phase transformations at the nanoscale with full field transmission X-ray microscopy. F. Meirer, J. Cabana, Y. Liu, A. Mehta, J. C. Andrews and P. Pianetta. J. Synch. Rad. 2011, 18, 773-781.

Comparison of the performance of LiNi1/2Mn3/2O4 with different microstructures. J. Cabana, H. Zheng, A. K. Shukla, C. Kim, V. S. Battaglia and M. Kunduraci. J. Electrochem. Soc. 2011, 158, A997–A1004.

Beyond intercalation-based Li-ion batteries: State of the art and challenges of electrode materials reacting through conversion reactions. J. Cabana, L. Monconduit, D. Larcher and M. R. Palacín. Adv. Mater. 2010, 22, E170-E192.

Structural complexity of layered-spinel composite electrodes for Li-ion batteries. J. Cabana, C. S. Johnson, S.-H. Kang, X.-Q. Yang, K.-Y. Chung, W.-S. Yoon, M. M. Thackeray and C. P. Grey. J. Mater. Res. 2010, 25, 1601-1616.

Exploring order-disorder structural transitions in the Li-Nb-N-O system: the new antifluorite oxynitride Li11NbN4O2. J. Cabana, M. Casas-Cabanas, H. J. Santner, A. Fuertes and M. R. Palacín. J. Solid State Chem. 2010, 183, 1609-1614.

MAS NMR study of the metastable solid solutions found in the LiFePO4/FePO4 system. J. Cabana, J. Shirakawa, G. Chen, T. J. Richardson and C. P. Grey. Chem. Mater. 2010, 22, 1249-1262.

Investigation of the structural changes in Li[NiyMnyCo(1-2y)]O2 (y = 0.05) upon electrochemical lithium deintercalation. D. Zeng, J. Cabana, W.-S. Yoon and C. P. Grey. Chem. Mater. 2010, 22, 1209-1219.

High rate performance of lithium manganese nitride and oxynitride as negative electrodes in lithium batteries. J. Cabana, C. M. Ionica-Bousquet, C. P. Grey and M. R. Palacín. Electrochem. Commun. 2010, 12, 315-318.

Structural and electrochemical characterization of composite layered-spinel electrodes containing Ni and Mn for Li-ion batteries. J. Cabana, S.-H. Kang, C. S. Johnson, M. M. Thackeray and C. P. Grey. J. Electrochem. Soc. 2009, 156, A730-A736.

Synthesis, short-range structure, and electrochemical properties of new phases in the Li−Mn−N−O system. J. Cabana, N. Dupré, F. Gillot, A. V. Chadwick, C. P. Grey and M. R. Palacín. Inorg. Chem. 2009, 48, 5141-5153.

The effects of moderate thermal treatments under air on LiFePO4-based nano powders. S. Hamelet, P. Gibot, M. Casas-Cabanas, D. Bonnin, C. P. Grey, J. Cabana, J.-B. Leriche, J. Rodriguez-Carvajal, M. Courty, S. Levasseur, P. Carlach, M. Van Thournout, J.-M. Tarascon and C. Masquelier. J. Mater. Chem. 2009, 19, 3979-3991.

Influence of the benzoquinone sorption on the structure and electrochemical performance of the MIL-53(Fe) hybrid porous material in a Lithium-ion battery. G. de Combarieu, M. Morcrette, F. Millange, N. Guillou, J. Cabana, C. P. Grey, I. Margiolaki, G. Férey and J.-M. Tarascon. Chem. Mater. 2009, 21, 1602-1611.


Publications while in supervised positions:

Formation of a complete solid solution between the triphylite and fayalite olivine structures. N. Recham, M. Casas-Cabanas, J. Cabana, C. P. Grey, J-C. Jumas, L. Dupont, M. Armand and J-M. Tarascon. Chem. Mater. 2008, 20, 6798-6809.

Towards new negative electrode materials for Li-ion batteries: Electrochemical properties of LiNiN. J. Cabana, Z. Stoeva, J. J. Titman, D.H. Gregory and M. R. Palacín. Chem. Mater. 2008, 20, 1676-1678.

Cation ordering in Li[NixMnxCo(1-2x)]O2 layered cathode materials: an NMR, pair distribution function, X-ray absorption spectroscopy and electrochemical study. D. Zeng, J. Cabana, J. Bréger, W.-S. Yoon and C. P. Grey. Chem. Mater. 2007, 19, 6277-6289.

NMR, PDF and RMC study of the positive electrode material Li(Ni0.5Mn0.5)O2 synthesized by ion-exchange methods.J. Bréger, K. Kang, J. Cabana, G. Ceder and C. P. Grey. J. Mater. Chem. 2007, 17, 3167-3174.

Intermediate phases during alkali metal intercalation in HfNCl. J. Oró-Solé, V. Meignen, J. Cabana, M. R. Palacín and A. Fuertes. Solid State Sci. 2007, 9, 310-317.

Enhanced high rate performance of LiMn2O4 spinel nanoparticles synthesized by a hard-template route.J. Cabana, T. Valdés-Solís, M. R. Palacín, J. Oró-Solé, A. Fuertes, G. Marbán and A.B. Fuertes. J. Power Sources 2007, 166, 492-498.

Layered oxysulfides Sr2MnO2Cu2m-0.5Sm+1 (m = 1, 2, and 3) as insertion hosts for Li ion batteries. S. Indris, J. Cabana, O. J. Rutt, S. J. Clarke and C. P. Grey. J. Am. Chem. Soc. 2006, 128, 13354-13355.

Oxynitrides as electrode materials for Lithium ion batteries: characterisation and performance of Li7.9MnN3.2O1.6. J. Cabana, N. Dupré, C. P. Grey, M. T. Caldés, G Subias and M. R. Palacín. J. Electrochem. Soc. 2005, 152, A2246-A2255.

Synthesis and electrochemical study of antifluorite-type phases in the Li-M-N-O (M = Ti, V) systems.J. Cabana, C. Mercier, D. Gautier and M. R. Palacín. Z. Anorg. Allg. Chem. 2005, 631, 2136-2141.

Ex situ NMR and neutron diffraction study of structure and lithium motion in Li7MnN4. J. Cabana, N. Dupré, G. Rousse, C. P.Grey and M. R. Palacín. Solid State Ionics 2005, 176, 2205-2218.

Anti-fluorite type lithium chromium oxide nitrides: relationships among synthesis, structure, order, and electrochemical properties.J. Cabana, C. D. Ling, J. Oró-Solé, D. Gautier, G. Tobías, S. Adams, E. Canadell and M. R. Palacín. Inorg. Chem. 2004, 43, 7050-7060.

The first lithium manganese oxynitride, Li7.9MnN5-yOy: preparation and use as electrode material in lithium batteries.J. Cabana, G. Rousse, A. Fuertes and M. R. Palacín. J. Mater. Chem. 2003, 13, 2402-2404.